Manipulation of Matrix-Isolated Molecules and Molecular Clusters with Electrostatic Fields
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This book demonstrates a combination of the ice film nanocapacitor method and the matrix isolation technique enabled the application of intense external dc electric fields across the isolated molecules and molecular clusters. Changes in molecular states induced by fields were monitored by means of vibrational spectroscopy. Also, the book presents manipulations of the inversion tunneling dynamics of ammonia molecule and the dislocation of acidic proton in hydrogen chloride-water complex.
The book shows that the vibrational spectroscopy with the aid of unprecedentedly strong dc electric field can provide rich information on the electrostatic behaviors of molecules and molecular clusters, which underlie the understanding of intermolecular processes and molecular manipulation.
1.1. Manipulation of Molecules with External Fields
1.2. Manipulation of Molecules with Homogeneous Electrostatic Fields
1.3. Approach and Contents of This Dissertation
Chapter 2. Method
2.1. A Combined Technique of Ice Film Nanocapacitor and Matrix Isolation
2.2. Reflection-Absorption Infrared Spectroscopy of Matrix-Isolated Molecules under the Influence of External Fields
Chapter 3. Electric Field-Control of Inversion Dynamics of Ammonia in an Argon Matrix
3.2. Experimental Details
3.3. Results and Discussion
Chapter 4. Spectroscopic Evidence of Large Protonic Polarizability of Hydrogen Chloride-Water Complexes
Chapter 5. Summary